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Faculty of Science, Engineering and Computing.
Penrhyn Road
Kingston upon Thames
Surrey KT1 2EE

Tel: +44 (0)20 8417 9000

Dr Andrew Chapman

School/Department: Life Sciences, Pharmacy & Chemistry
Position: Lecturer In Inorganic Chemistry

Educational and Professional Qualifications

  • 2008 - 2011 PhD - University of Bristol
  • 2003 - 2007 MSci Chemistry, University of Bristol

Research Interests

Current activities:

Proof-of-concept Cu-tracers for in vivo imaging of NO using PET and 19F MRi

Synthesis of new polymers

New catalytic transformations using the concept of ligand-metal participation

Publications:

Chapman, A. M.; Flynn, S.; Wass, D. F.; Facile, reversible insertion of Pt into Zr-C bonds: Synthesis of a rare T-shaped Pt complex with an 'organometallic Z-type ligand.', In review; Submitted (Inorg. chem.) June 2015.

Hazeland, E. L., Chapman, A. M., Pringle, P; One-step, modular route to optically active diphos ligands.' Chem. Commun. 2015, 51, 10206-10209.

Cano I., Chapman A. M., Huertos, M. A., van Leeuwen P. W. N. M. Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemoselective Hydrogenation of Substituted Aldehydes: a Remarkable Ligand Effect, J. Am. Chem. Soc., 2015, 137 (24), 7718–7727

Chapman, A. M.; Keyworth, C., Kember, M. Lennox, A., Williams, C., 'Adding value to Power-Station Captured CO2: Highly tolerant bimetallic Zn and Mg homogeneous catalysts for polycarbonate polyol production', ACS catalysis., 2015, 5, 1581-1588.

Metters, O., Chapman, A. M., Robertson, A., Woodall, C., Gates, P., Wass, D., Manners, I., Generation of Aminoborane Monomers from Amine-Boronium Cations: Metal Catalyst-Free Formation of Polyaminoboranes at Ambient Temperature. Chem. Comm., 2014, 50, 12146-12149.

Cano I., Chapman A. M., Urakawa A. and van Leeuwen P. W. N. M. Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides for the Chemoselective Hydrogenation of Aldehydes: Crucial Role of the Ligand. J. Am. Chem. Soc., 2013, 136(6), 2520-2528. (Highlighted and re-printed in Synfacts, 2014, 10(5), 0547).

Chapman, A. M.; Wass, D. F.; Frustrated Lewis pairs beyond the main group: transition metal-containing systems.. Book Chapter, Topics in Current Chemistry, 2013, 334, 261-280.

Trentin, F., Chapman, A. M., Scarso, A., Sgarbossa, P., Michelin, R. A., Strukul, G., Wass, D. F., Platinum(II) Diphosphinamine Complexes for the Efficient Hydration of Alkynes in Micellar Media. Adv. Synth. Catal., 2012, 354, 1615.

Chapman, A. M.; Wass, D. F.; Cationic Ti(IV) and neutral Ti(III) titanocene-phosphinoaryloxide frustrated Lewis pairs: hydrogen activation and catalytic amine-borane dehydrogenation.' Dalton Trans., 2012, 41, 9067

Chapman, A. M.; Haddow, M. F.; Wass, D. F.; Cationic group 4 metallocenephosphinoaryloxide complexes: Synthetic routes to transition metal frustrated Lewis pairs.' Eur. J. Inorg. Chem., 2011, 1099.

Chapman, A. M.; Haddow, M. F.; Wass, D. F.; 'Frustrated Lewis pairs beyond the main group: synthesis, reactivity and small molecule activation with cationic zirconocene-phosphinoaryloxide complexes.' J. Am. Chem. Soc., 2011, 133, 18463.

Chapman, A. M.; Haddow, M. F.; Wass, D. F.; Frustrated Lewis Pairs beyond the
Main Group: Cationic zirconocene phosphinoaryloxide complexes and their application in catalytic dehydrogenation of amine-boranes.' J. Am. Chem. Soc., 2011,133, 8826.

Chapman, A. M.; Haddow, M. F.; Orton, J. P. H.; Wass, D. F.; 'Facile dihydrogen release from phosphino-borinate ester Lewis pairs.' Dalton Trans., 2010, 39, 6184.

Teaching Area

Inorganic and supramolecular chemistry

Other Professional Activity

Consultant Research & Development Chef (Chef events, London, http://www.chefevents.co.uk/)

RSC Member

Reaxys Prize Club member


    +Professional Experience

Details

Email:
A.Chapman@kingston.ac.uk

Phone:
62398

Location:
PRMB2011